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Herein, we intend to focus on the mechanistic aspect of the methanol synthesis from CO 2 hydrogenation over metal-based catalysts, including Cu-, precious metal-, and other catalysts (composite-, Oxygen deficient- and oxide-based catalyst). Download : Download high-res image (242KB) Download : Download full-size image.

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Hence, methanol synthesis over Cu appears to be a structure-sensitive reaction. Single-crystal studies ( 9–11) report turnover frequencies (TOF) for methanol synthesis ranging from as low as 1.3 × 10 −6 to 6 × 10 −3 s −1 per site. ZnO functions as a physical spacer between Cu NPs and helps disperse the Cu phase in the course of ...

Methanol is an important industrial chemical and liquid fuel, and is usually produced by the syn-gas route from natural gas. Wuet al. develop a new catalytic process that directly converts ...

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